Article ID Journal Published Year Pages File Type
1194265 International Journal of Mass Spectrometry 2008 5 Pages PDF
Abstract
An electron impact (EI) ion source and a double focusing sector field mass spectrometer were used to investigate ionization processes of acrylonitrile C3H3N. The ionization and appearance energies for observed singly CxHyNz+ (x = 1-3; y = 0, 1, 3; z = 0, 1) and doubly C3H3N2+ and C3HN2+ charged ions were determined by using the non-linear least-square fitting procedure to the raising set of the data points. In the case of ions: C2HN+/C3H3+, C2N+/C3H2+, C3H+, C3+, CH2N+, CHN+/C2H3+, C2H+, C2+, H2N+, HN+/CH3+, CH2+/N+, CH+, C+, C3H3N2+ and C3HN2+ these energies were obtained for the first time.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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