Article ID Journal Published Year Pages File Type
1194457 International Journal of Mass Spectrometry 2008 6 Pages PDF
Abstract

The MS and MSn fragmentation pathways of polyamide/IDB (IDB = bis(2-benzimidazolylmethyl)amine) conjugates, which are synthesized as potent artificial nucleases, are discussed. The main fragmentation pathways occur by the cleavage of the CCO bonds between N-methylpyrrole and carbonyl groups. Electrospray ionization is proven to be a good method for the structural characterization and identification of this kind of compounds.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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