Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1194723 | International Journal of Mass Spectrometry | 2006 | 6 Pages |
Abstract
Rate constants and product distributions have been measured for a number of simple molecules reacting with ONOOâ at 200 and 300Â K. NO, CO, H2, CH4, N2O, and H2O did not react with ONOOâ. HCl and HCN underwent proton transfer in addition to other competing channels. Charge transfer from ONOOâ was observed exclusively with O3 and NO2. SO2 and HCl underwent exchange for NO in ONOOâ. HCN was the only substance to show substantial chemistry, producing CNOâ and NO2â in addition to the proton transfer channel. Rate constants for the reactive substances were generally rapid, occurring at >10% of the collision rate constant.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
A.A. Viggiano, Anthony J. Midey, A. Ehlerding,