| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1195467 | Journal of the American Society for Mass Spectrometry | 2008 | 11 Pages |
Abstract
The kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn2+ exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn2+ prefers to be solvated by methanol in the primary solvation shell.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Bridgette J. Duncombe, Jens O.S. Rydén, Ljilijana Puškar, Hazel Cox, Anthony J. Stace,