| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1195529 | Journal of the American Society for Mass Spectrometry | 2007 | 8 Pages |
Abstract
A hitherto unknown, isotope-exchange reaction is studied in ionized gaseous mixtures containing disulfur monoxide and water. The kinetics, mechanism, and intermediate of the reaction are investigated by experimental and theoretical methods. The reactivity of the S2O˙+ cation with water is investigated under a wide range of pressures ranging from 10−7 to 10−4 Torr, by FT-ICR, TQ, and high-resolution CAD mass spectrometry. In the high-pressure limit the reaction proves to be a route to strongly bound sulfur-containing species.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Giulia de Petris, Anna Troiani, Giancarlo Angelini, Ornella Ursini, Andrea Bottoni, Matteo Calvaresi,