| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1195653 | Journal of the American Society for Mass Spectrometry | 2010 | 7 Pages |
Saturated nonfunctionalized hydrocarbons can be oxidized in situ by initiating an electrical discharge during desorption electrospray ionization (DESI) to generate the corresponding alchohols and ketones. This form of reactive DESI experiment can be utilized as an in situ derivatization method for rapid and direct analysis of alkanes at atmospheric pressure without sample preparation. Betaine aldehyde was incorporated into the DESI spray solution to improve the sensitivity of detecting the long-chain alcohol oxidation products. The limit of detection for alkanes (C15H32 to C30H62) from pure samples is ∼20 ng. Multiple oxidations and dehydrogenations occurred during the DESI discharge, but no hydrocarbon fragmentation was observed, even for highly branched squalane. Using exact mass measurements, the technique was successfully implemented for analysis of petroleum distillates containing saturated hydrocarbons.
Graphical AbstractDeliberately generated electrical discharges during DESI allow rapid and direct analysis of petroleum distillates in the open air through in situ oxidation of non-functionalized hydrocarbons.Figure optionsDownload full-size imageDownload high-quality image (173 K)Download as PowerPoint slide
