Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1196254 | Journal of the American Society for Mass Spectrometry | 2016 | 8 Pages |
Abstract
The traditional solvent-based matrix-assisted laser desorption ionization (MALDI) preparation method has been used to analyze nonpolar polymers of various molecular weights. High resolution silver cationized oligomers with masses of up to 12 KDa were measured using 9.4 tesla Fourier transform mass spectrometry (FTMS) with an external ionization source. It was observed that when time-of-flight mass spectrometry was used, the spectra of polyethylene polymers showed abundant low mass fragment ions. However, these fragments were absent from the FTMS spectra.
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Authors
Arwah J. Jaber, Charles L. Wilkins,