| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1196937 | Journal of Analytical and Applied Pyrolysis | 2013 | 8 Pages |
Rhubarb has been used as a tobacco additive recently. In order to understand the smoke emissions of herbal cigarettes with rhubarb additive, the pyrolysis of major components of rhubarb: chrysophanol and its derivatives (emodin, rhein and aloe-emodin) have been studied by synchrotron VUV photoionization mass spectrometry (SVUV-PIMS) combined with molecular-beam sampling technique. Various pyrolysis products are observed due to the different substituent groups. The main pyrolysis products of chrysophanol come from the CO and H2O elimination reactions. The CO, CO2 and HCOOH elimination reactions are the primary pyrolysis processes for rhein. Besides, elimination of H2 from aloe-emodin and loss of OH radical from both emodin and rhein also occur in the pyrolysis process. Furthermore, theoretical calculations are used to deduce the decomposition pathways and determine the geometries of pyrolysis products. Our work shows that the combination of SVUV-PIMS measurements and theoretical calculations is powerful to study pyrolysis behavior of complex organic compounds.
► Pyrolysis behavior of chrysophanol and its derivatives was studied by SVUV-PIMS. ► Tunable SVUV photoionization benefits the measurement of pyrolytic products. ► The initial formation temperatures of all pyrolytic products have been determined. ► Theoretical calculations validated the decomposition pathways of studied compounds. ► SVUV-PIMS combined theoretical calculations perform well in pyrolysis analysis.
