Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1210593 | Journal of Chromatography A | 2006 | 7 Pages |
Abstract
The behaviour and separation characteristics of capillary columns containing different stationary phases (bonded methyl- and methylphenylsiloxanes and polyglycols, and carbon layer and porous polymer) were classified and compared by measuring the values of the solution enthalpy ÎHs of n-alkanes and 1-alcohols at various temperatures. The difference in ÎHs values between straight-chain 1-alcohols and n-alkanes with the same number of carbon atom (ÎÎHs) does not change with changing temperature when gas-liquid partition stationary phases are used, but depends on the column composition and polarity and therefore permits to evaluate the influence of polarity on the solute-solvent interaction. The trend of the ÎÎHs values is correlated with that of the ÎC parameter and with the McReynolds' polarity constants.
Keywords
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Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
S. Vezzani, P. Moretti, G. Castello,