| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1210611 | Journal of Chromatography A | 2009 | 4 Pages |
Abstract
Monolithic silica columns in semi-micro-format have been synthesized using poly(acrylic acid) as a phase-separation inducer via a sol–gel route. The absence of a thick skin layer accompanied by deformation of the micrometer-sized gelling skeletons on the outermost part of the macroporous silica rod contributed to improve the efficiency of monolithic silica columns as thick as 2.4 mm in diameter. The kinetic plot analysis revealed that monolithic silica columns with macropore diameter of 1 μm and skeleton thickness of 1 μm with decreased macroporosity behave similarly to columns packed with 3 μm particles with slightly lower back pressure.
Related Topics
Physical Sciences and Engineering
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Analytical Chemistry
Authors
Kei Morisato, Shota Miyazaki, Masayoshi Ohira, Masahiro Furuno, Masahiko Nyudo, Hiroyuki Terashima, Kazuki Nakanishi,