| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1229058 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2015 | 7 Pages |
•Silver nanoparticles were synthesized using combustion method.•It is fcc crystalline structure with rod like shape.•Spectral analysis reveals that BrS is adsorbed on the silver surface by tilted orientation.•Theoretical calculations performed to study the vibrational features of BrS.
SERS provides essential data regarding the interaction of molecules in drugs with DNA. In the present study silver nanoparticles were synthesized using a solution combustion method with urea as fuel. The prepared silver nanoparticles are rod like structure. Surface-enhanced Raman scattering (SERS) of N-(1-2-bromophenyl)-2-(2-nitrophenyl)ethyl)-4-methylbenzenesulfonamide (BrS) adsorbed on the silver nanoparticle was studied. The nRs and Raman spectral analysis reveal that the BrS adsorbed tilted orientation on the silver surface. Vibrational modes of nRs along with HF calculations are also performed to study the HOMO and LUMO behavior and vibrational features of BrS.
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