Article ID Journal Published Year Pages File Type
1229283 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2015 5 Pages PDF
Abstract

•The mineral yuksporite has been analyzed.•Scanning electron microscopy shows a single pure phase with cleavage fragment up to 1.0 mm.•Chemical analysis gave Si, Al, K, Na and Ti as the as major elements with small amounts of Mn, Ca, Fe and REE.•The mineral was characterized by vibrational spectroscopy.

The mineral yuksporite (K,Ba)NaCa2(Si,Ti)4O11(F,OH)⋅H2O has been studied using the combination of SEM with EDX and vibrational spectroscopic techniques of Raman and infrared spectroscopy. Scanning electron microscopy shows a single pure phase with cleavage fragment up to 1.0 mm. Chemical analysis gave Si, Al, K, Na and Ti as the as major elements with small amounts of Mn, Ca, Fe and REE. Raman bands are observed at 808, 871, 930, 954, 980 and 1087 cm−1 and are typical bands for a natural zeolite. Intense Raman bands are observed at 514, 643 and 668 cm−1. A very sharp band is observed at 3668 cm−1 and is attributed to the OH stretching vibration of OH units associated with Si and Ti. Raman bands resolved at 3298, 3460, 3562 and 3628 cm−1 are assigned to water stretching vibrations.

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Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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