| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1231385 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2016 | 5 Pages |
•Four hemicyanine dyes as chemosensors for cyanide anions were synthesized easily.•All the dyes allow for ‘naked-eye’ detection of cyanide anions.•To compounds without hydroxyl group, CN− is bonded to CC in conjugated bridge.•To compounds with hydroxyl, mechanism is intramolecular hydrogen bonding action.
Four hemicyanine dyes as chemosensors for cyanide anions were synthesized easily. Their photophysical properties and recognition properties for cyanide anions were investigated. The results indicate that all the dyes can recognize cyanide anions with obvious color, absorption and fluorescence change. The recognition mechanism analysis basing on in situ 1H NMR and Job plot data indicates that to the compounds with hydroxyl group, the recognition mechanism is intramolecular hydrogen bonding interaction. However, to the compounds without hydroxyl group, cyanide anion is bonded to carbon–carbon double bond in conjugated bridge and induces N+ CH3 to neutral NCH3. Fluorescence of the compounds is almost quenched upon the addition of cyanide anions.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
