Article ID Journal Published Year Pages File Type
1231536 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2013 9 Pages PDF
Abstract

In the present work, photophysical behaviour of 8-amino 2-naphthol in various solvents as well as at various pH values has been investigated. Various ground and excited state species are noticed. It exhibits a completely different photo prototropic behaviour as compared to its parent molecule 2-naphthol. The spectral and transient studies indicate that at lower pH values, equilibrium between cation and neutral exists in the excited state. At neutral pH some peculiar behaviour in its spectral properties is noticed.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Spectral and time resolved properties of 8-amino-2-naphthol are investigated. ► Some interesting pH dependent features for this compound are noticed. ► At lower pH (1.7), cation/neutral dynamic equilibrium exists in the excited state. ► At neutral pH, it exhibits larger Stokes shifted emission. ► The spectral signatures indicate various emitting/absorbing species.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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