Article ID Journal Published Year Pages File Type
1232330 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012 6 Pages PDF
Abstract

A novel colorimetric chemosensor based on aminonaphthoquinone (L) bearing an N–H receptor unit directly attached to quinone signaling unit has been designed, synthesized and demonstrated. The ligand showed a highly selective colorimetric response to fluoride ions based on H-bond formation with the receptor unit. The binding constants of the L and its square planar [Co(L)Cl2]·3H2O and [Ni(L)Cl2]·4H2O complexes, computed using fluorescent enhancement data, were found to be 0.6, 1.5 and 0.9 × 108 M−1, respectively, indicating enhancement of H-bond donor ability of the receptor unit, as a result of complexation with metal ions, towards fluoride ion sensing. Also, these sensors had high selectivity for fluoride ion detection over other common anions, such as Cl−, Br−, I−, AcO−, NO3−, H2PO4− and CN− in acetonitrile.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The developed sensor selectively detects fluoride ions in acetonitrile. ► The chemosensor is novel with sensing unit directly attached to the signaling unit for easy signaling. ► The mechanism of the colorimetric sensing is through H-bond formation between N–H moiety and fluoride ions.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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