Article ID Journal Published Year Pages File Type
1232485 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2015 8 Pages PDF
Abstract

•Fluorescence spectral results demonstrate evidence of Cr2O72−–HA interaction.•The interaction between Cr2O72− and HA is not strong.•The hydrogen bonding, hydrophobic and electrostatic forces are involved in the binding process.•The hydrophobic binding cavities of HA play a key role in binding with Cr2O72−.

In this report, the binding interaction of chromium(VI), as Cr2O72−, with humic acid was studied by using UV–visible absorption, fluorescence spectroscopy, and molecular modeling method. The fluorescence spectral data indicated that the binding interaction existed between Cr2O72− and humic acid and the order of magnitude of binding constants were 103. The rise in temperature caused a decrease in the values of the binding constant of humic acid with Cr2O72−. Thermodynamic analysis presented that multi-intermolecular forces including hydrogen bonding, hydrophobic, and electrostatic forces were involved in the binding process at pH 6.5. The spectral data also indicated that Cr2O72− affected the aromatic ring structures in humic acid. Furthermore, the molecular modeling analysis indicated that a lot of reactive groups and binding cavities in HA played a key role in its binding with Cr2O72−.

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Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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