| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1232601 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2012 | 4 Pages |
By the reaction of Zn(OAc)2·2H2O with Ozagrel, (E)-3-(4-((1H-imidazol-1-yl)methyl)phenyl)acrylic acid (Himpaa), a novel coordination polymer [Zn(impaa)2]n(1) was synthesized and was characterized by IR, elemental analysis, single-crystal X-ray diffraction analysis, photoluminescence spectroscopy, and thermogravimetric and differential thermal analysis. The four-coordinate Zn(II) ions are linked into 1D double-helical chain by the deprotonated impaa−, which is extended into a 3D supramolecular structure through intermolecular C–H⋯O hydrogen bonds.
Graphical abstractA novel coordination polymer [Zn(imppa)2]n {Himppa = (E)-3-(4-((1H-imidazol-1-yl)methyl)phenyl)acrylic acid} contains double-helical chains that are extended into a 3D supramolecular structure through intermolecular C–H⋯O hydrogen bonds.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The zinc(II) coordination polymer with Ozagrel. ► 1D double-helical chain. ► 3D supramolecular structure through intermolecular C–H⋯O hydrogen bonds.
