Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1232641 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2012 | 6 Pages |
The 1:1, 1:2 and 2:1 formaldoxime-water complexes isolated in the argon matrices have been studied by help of FTIR spectroscopy and MP2/6-311++G(2d,2p) method. The calculations predicted the stability of the three CH2NOH⋯H2O isomeric complexes, three CH2NOH⋯(H2O)2 ones and one (CH2NOH)2⋯H2O complex. The analysis of the experimental spectra and their comparison with theoretical ones indicated that both the 1:1 and 1:2 complexes trapped in solid argon have the most stable cyclic structures stabilized by the O–H⋯O and O–H⋯N bonds between the formaldoxime and water molecules. In the 1:2 complex formaldoxime interacts with the water dimer, one H2O molecule acts as a proton acceptor for the OH group of formaldoxime whereas the second H2O molecule acts as a proton donor toward the nitrogen atom of the formaldoxime molecule. In the (CH2NOH)2⋯H2O complex the OH group of the water molecule acts as a proton donor toward one of the oxygen atoms of the formaldoxime cyclic dimer.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The 1:1, 1:2 and 2:1 formaldoxime–water complexes are formed in the argon matrices. ► The 1:1 and 1:2 cyclic CH2NOH–H2O complexes are stabilized by N⋯H–O and O–H⋯O bonds. ► The deviation of hydrogen bonds from linearity decreases the hydrogen bond strength. ► In the 2:1 complex water is attached to an oxygen atom of the formaldoxime cyclic dimer.