Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1232812 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2014 | 5 Pages |
•A blue-white long persistent phosphor.•Zn imperfections as emitting centers without any rare-earth doping.•An energy transfer and remission process is proposed.
The recombination luminescence from Zn imperfections has been extensively investigated; however, there have been few reports on the long persistent luminescence of Zn imperfections as emitting centers. Here, we observed a long persistent luminescence in blue-white visible region from 6 ZnO:3 GeO2:Al2O3 phosphor with Zn imperfections as emitting centers. Persistent luminescence could be observed beyond 2 h with naked eyes. The properties of traps were also elaborated by the measurements of thermo-luminescence spectra and photo-stimulated luminescence decay curves. Furthermore, a long persistent phosphor with warm white color was developed by doping Cr3+ into 6 ZnO:3 GeO2:Al2O3 phosphor.
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