| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1232929 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2011 | 6 Pages |
Abstract
Infrared (IR) spectroscopic studies of mineral and synthetic phosphates have been presented. The interpretation of the spectra has been preceded by the isolated [PO4]3− tetrahedron spectra analyse. The K3PO4 saturated aqueous solution was measured in the special cell for liquids. The obtained IR results have been compared with the theoretical number of IR-active modes. The number and positions of the bands due to P–O vibrations have been established.The phase composition of the phosphates has been determined using XRD and IR spectroscopy methods. The influence of non-tetrahedral cations on the shape of the spectra and the positions of bands has been analysed and the crystalline field splitting effect has been discussed.
Keywords
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Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
W. Jastrzębski, M. Sitarz, M. Rokita, K. Bułat,