Article ID Journal Published Year Pages File Type
1233000 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012 6 Pages PDF
Abstract

Three highly sensitive and selective switches for monosaccharides were composed by anionic polyelectrolyte PPPSO3Na and cationic viologen quencheres BBVs. The sensing processes of three ensembles (PPPSO3Na/o-BBV, PPPSO3Na/m-BBV and PPPSO3Na/p-BBV) to common seven monosaccharides have been determined by fluorescence spectra at pH 7.4 buffer solution. The results show that the three sensing ensembles all embody higher selectivity and sensitivity for d-fructose with reversible “on-off-on” fluorescence response. The research results can provide a new mode for developing highly selective probes.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► In the study we establish three sensing ensembles for d-monosaccharides. ► These sensing ensembles are comprised of polyelectrolyte and BBVs quenchers. ► The ensembles all show high selectivity and sensitivity for d-fructose in seven monosaccharides. ► The research results can provide a new strategy for molecular recognition.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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