| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1233317 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2011 | 6 Pages |
Abstract
New Hofmann type clathrates in the form of M(pp)2Ni(CN)4·2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of |M–Ni(CN)4|∞ with the pp bound to the metal (M) atom.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Vibrational investigation of Hofmann type clathrates. ► Using a non-aromatic guest molecule as 1,4-dioxane. ► The host–guest interactions are weak. ► The trapped 1,4-dioxane guest molecules have kept their free forms.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Cemal Parlak, Mustafa Şenyel,