Article ID Journal Published Year Pages File Type
1233320 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2011 4 Pages PDF
Abstract

Tb3+ and Gd3+ ions doped lithium–barium–aluminosilicate oxyfluoride glasses have been prepared. The transmission, emission and excitation spectra were measured. It has been found that those Tb3+-doped lithium–barium–aluminosilicate oxyfluoride glasses exhibit good UV-excited luminescence. The luminescence intensity of Tb3+ ion increases for those (Tb3+, Gd3+)-codoped glasses. Energy transfer process from Gd3+ ion to Tb3+ ion is indicated.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Different concentration Tb3+-doped and (Tb3+, Gd3+)-codoped lithium–barium–aluminosilicate oxyfluoride glasses were fabricated by melt-quenching method. ► 5D4 → 7Fj emissions are enhanced in Tb3+-doped lithium–barium–aluminosilicate oxyfluoride glasses with the increase of Tb3+ ion concentration. ► Gd3+ ion sensitizes Tb3+ ion and enhances the luminescence intensity of Tb3+ ions in (Tb3+, Gd3+)-codoped lithium–barium–aluminosilicate oxyfluoride glasses.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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