| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1233666 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2010 | 5 Pages |
Abstract
The polyoxometalate-based 1D coordination polymer [Cu(DMF)6][PMoVMoVI11O40Cu(DMF)4]·DMF 1 was synthesized and characterized by IR, UV spectroscopy and single-crystal X-ray diffraction analysis. Each Cu(II) center has a distorted octahedral coordination geometry. Cu(1) center interconnects with two [PMoVMoVI11O40]4− anion subunits and each [PMoVMoVI11O40]4− polyoxoanion acts as a didentate ligand to link two Cu centers through two terminal oxygen atoms to form a one-dimensional chain structure. The luminescent properties of 1 in the solution and in the solid state were investigated, respectively.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
![A one-dimensional polyoxometalate-based polymer [Cu(DMF)6][PMoVMoVI11O40Cu(DMF)4]·DMF: Crystal structure and luminescent properties](/preview/png/1233666.png "First Page Preview: A one-dimensional polyoxometalate-based polymer [Cu(DMF)6][PMoVMoVI11O40Cu(DMF)4]·DMF: Crystal structure and luminescent properties")
Authors
Yan Bai, Guang-Shui Zheng, Dong-Bin Dang, Hui Gao, Ze-Yan Qi, Jing-Yang Niu,