Article ID Journal Published Year Pages File Type
1233890 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2008 4 Pages PDF
Abstract

The electronic structures and substituent effects of o-, m-, and p-chloronitrobenzene and bromonitrobenzene have been studied by ultraviolet photoelectron spectroscopy (UPS). It was found that the o-isomer possesses particular electronic properties. This characteristic depends on the conjugation between the benzene ring π orbital and the nitro group π orbital and the interaction of the halogen and nitro groups in the adjacent position.

Graphical abstractThe electronic structures and substituent effects of o-, m-, and p-chloronitrobenzene and bromonitrobenzene have been studied by ultraviolet photoelectron spectroscopy (UPS). It was found that the o-isomer possesses particular electronic properties. This characteristic depends on the conjugation between the benzene ring π orbital and the nitro group π orbital and the interaction of the halogen and nitro groups in the adjacent position.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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