Article ID Journal Published Year Pages File Type
1234447 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012 6 Pages PDF
Abstract

A new artificial receptor 1 was synthesized for the detection of Fe3+ and Mg2+ in solution as a colorimetric and fluorescent sensor, respectively. The sensor exhibited highly selective and sensitive recognition towards Fe3+ in CH3CN via color change from colorless to brown. Also it showed a significant fluorescence enhancement (70-fold) towards Mg2+ in the mixture of solution CH3CN/H2O (8:2, v/v). The selectivity of either Fe3+ or Mg2+ was not interfered by the presence of other metal ions such as Cr3+, Mn2+, Co3+, Ni2+, Cu2+, Ag+, Cd2+, Pb2+, Ca2+ and K+ ions.

Graphical abstractDual chemosensing properties of new selective colorimetric chemosensor for Fe3+ and fluorescent sensor for Mg2+ cations based on coumarin derivative.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The coumarin based receptor could be used as a selective sensor for Fe3+ ions by using UV–vis. ► And as well as Mg2+ ions by using fluorescence methods. ► It has an advantage of naked eye determination without using any costly instruments.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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