Article ID Journal Published Year Pages File Type
1234520 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2009 6 Pages PDF
Abstract

Bis-[methylsalicylidine-4′benzoic acid]-ethylene (LH2) complexed with cis-Ru(bpy)2Cl2·2H2O provides a complex of composition [Ru(bpy)2L]·2NH4PF6 (1), which has been characterized spectroscopically. Its binding behaviour towards Mg2+ and Ca2+ ions is monitored using 1H NMR titration, isothermal titration calorimetry (ITC) and luminescence microscopy. The luminescent ruthenium complex binds Ca2+ in a more selective manner as compared to Mg2+.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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