Article ID Journal Published Year Pages File Type
1234824 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2009 8 Pages PDF
Abstract

A pentakis benzimidazole based penta-amide ligand diethylenetriamine—N,N,N′,N′,N″-pentakis(2-methyl benzimidazolyl)penta-amide [GBDTPA] has been synthesized and utilized to prepare Mn (II) complexes of general composition [Mn2(GBDTPA)X4], where X is an exogenous anionic ligand (X = Cl−, NO3− and Br−). The oxidation of alcohols has been investigated using [Mn2(GBDTPA)Cl4] as the catalyst and TBHP as an alternate source of oxygen. The respective aldehydic products have been isolated and characterized by 1H NMR.

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Physical Sciences and Engineering Chemistry Analytical Chemistry
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