Article ID Journal Published Year Pages File Type
1234989 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2009 6 Pages PDF
Abstract

Quercetin (3,3′,4′,5,7-pentahydroxyflavone) one of the most abundant dietary flavonoids, has been investigated in the presence of Cu(II) in methanol. The spectroscopic studies (UV–vis, 1H NMR and IR) were useful to assess the relevant interaction of Quercetin with Cu(II) ions, the chelation sites and dependence of the complex structure from the metal/ligand ratio. A 1:2 (L:M) complex was indicated by Job's method of continuous variation, which was applied to ascertain the stoichiometric composition of the complex. The antioxidant activities of the compounds were evaluated by using the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging method. The complexed flavonoid was much more effective free radical scavengers than the free flavonoids.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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