Article ID Journal Published Year Pages File Type
1235097 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 6 Pages PDF
Abstract

To improve the selectivity ratio of C70 over C60, a new designer molecule, viz., 3-fluoromesotetraphenylporphyrin (1) has been reported in the present investigations. Fluoresence studies reveal that the Q-absorption band of 1 gets sufficient quenching effect upon addition of both C60 and C70. Binding constants (K) of the C60/1 and C70/1 complexes are estimated to be 580 and 10,800 dm3 mol−1, respectively. Thus, KC70/KC60KC70/KC60 is ∼19 which is very large and even comparable with other macrocyclic host molecules like calix[5]arene, azacalix[m]arene[n]pyridine, cyclotriveratrylenophane and calixarene bisporphyrin. 1H NMR chemical shift measurements show that the –NH– proton of 1 suffers more shifts in presence of C70 compared to C60. This finding also offers a good support in favor of high K value for C70/1 complex as well as large selectivity ratio of C70 over C60.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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