| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1235106 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2007 | 8 Pages |
Abstract
Methyl(2-methyl-4,6-dinitrophenylsulfanyl)ethanoate was prepared by nucleophilic substitution. FT-IR and FT-Raman spectra of methyl(2-methyl-4,6-dinitrophenylsulfanyl)ethanoate were recorded and analyzed. Surface-enhanced Raman scattering (SERS) spectrum was recorded on a silver colloid. The vibrationl wavenumbers were computed by density functional theoretical (DFT) computations at the B3LYP/6-31G* level and they were found to be in good agreement with the experimental values. The molecule is adsorbed on the silver surface with the benzene ring in a ‘tilted orientation’.
Keywords
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Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
C. Yohannan Panicker, Hema Tresa Varghese, Daizy Philip, Helena I.S. Nogueira, Katerina Castkova,