Article ID Journal Published Year Pages File Type
1235120 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 4 Pages PDF
Abstract

A novel and simple fluorescence enhancement method for selectively sensing iodide was proposed based on metal complex formation between mercuric(II) ion with fluorophore (p-((dimethylamino)benzylidene)thiosemicarbazide, 1) and with anion in aqueous solution. The 1–Hg complex was found to show selectively and sensitively fluorescence enhancement response toward iodide over than S2−, EDTA, SCN−, CH3CO2−, Br−, Cl−, F−, H2PO4− and SO42−, which was attributed to the higher stability of inorganic complex between iodide and mercuric(II).

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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