| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1235373 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2012 | 8 Pages |
The relative effect of hydrogen bonding of pyrimidine (Pyr) in H2O/D2O and pyridine (Py) in CH3OH/CD3OD has been analyzed using Raman Difference Spectroscopic (RDS) technique and DFT calculations. This study is focused on analyzing the concentration dependent variation of linewidth, peak position and intensity of ring breathing mode of Py and Pyr. The ring breathing mode of Pyr in H2O and D2O has three components; due to free Pyr, lighter complexes of mPyr + nH2O/D2O and heavier complexes of mPyr + nH2O/D2O. The pyridine molecules, however, show only two components in CH3OH and CD3OD. Of these two components, one corresponds to free Py and the other inhomogeneously broadened profile corresponds to all mPy + nCH3OH/CD3OD complexes. The variation of peak position and linewidth establishes the role of dipole moment of complexes and the diffusion in the mixture. In case of CD3OD solution splitting was observed in ∼1030 cm−1 band of Py, where an additional band at ∼1034 cm−1 appears at x(Py) ⩽ 0.4. However, this band remains single at all concentrations in case of CH3OH solvent.
Graphical abstractRaman spectra of pyridine with (a) methanol and (b) deuterated methanol.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► RDS technique is used to study the frequency shifts and linewidth. ► Hydrogen bonded complexes optimized in different stoichiometric ratios. ► The effect of deuteration was compared in H2O and CH3OH solvents. ► Role of diffusion coefficients and dipole moments on peak shift and linewidth changes emphasized.
