Article ID Journal Published Year Pages File Type
1235526 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 6 Pages PDF
Abstract

In this paper, SO32−-chemiluminescence (CL) system in unbuffered solution with ClO2 as oxidant is proposed. ClO2 could oxidize sulfite in unbuffered solution to produce CL emission, and riboflavin could sensitize the ClO2–SO32−-based CL system. The ClO2–SO32−–riboflavin CL reaction was chosen as a model system and explored the possibility of SO32−-based CL system in unbuffered solution. Compared with the reported SO32−-based CL system in strong acid media, the proposed CL system owns its advantages. Combined with flow-injection analysis, the proposed CL system was applied to measurement of riboflavin in pharmaceuticals.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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