Article ID Journal Published Year Pages File Type
1235690 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 5 Pages PDF
Abstract

The infrared absorption spectra of the androsterone in 19 pure organic solvents have been investigated. The carbonyl stretching vibration frequencies of androsterone observed in the solvents were correlated with the empirical parameters G, Swain parameters (Aj and Bj) and the linear solvation energy relationships (LSER). The applicabilities of different parameters were discussed and the solute–solvent interactions in single solvents were studied in detail. The correlation results indicated that the LSER is optimal for a complete description of solute–solvent interactions while G-values and Swain parameters are unilateral.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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