Article ID Journal Published Year Pages File Type
1235764 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 6 Pages PDF
Abstract

The chemiluminescence arising from the reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) with hydrogen peroxide in the presence of brightener 4,4′-bis{[4,6-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl]amino}stilbene-2,2′-disulfonic acid-disodium salt (Triazinyl) has been studied. The influence of concentration of TCPO, hydrogen peroxide, Triazinyl, base catalysts and temperature on the resulting chemiluminescence was investigated. The kinetic parameters for the peroxyoxalate-chemiluminescence (PO-CL) of Triazinyl were evaluated from computer fitting of the resulting intensity–time plots. The activation energies, Ea, were evaluated from temperature dependence of the corresponding rise and fall rate constants.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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