Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1235878 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2007 | 5 Pages |
Abstract
The fluorescence properties of p-sulfonated calix[4,6]arene (SCnA, n = 4, 6) in cationic surfactant cetyltrimethylammonium bromide (CTAB) solution were investigated. It was found that the fluorescence intensity of SCnA could be enhanced markedly by an appropriate amount of CTAB. The results indicate the formation of complex between CTAB and SCnA at a 1:1 complex stoichiometry and their association constants were calculated by applying a deduced equation. Based on the obtained results, a new fluorimetric method has been developed for rapid determination of SCnA with a good linearity in the concentration range of 2 × 10−7 to 7 × 10−6 mol L−1.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Yunyou Zhou, Chun Liu, Hongwei Xu, Huapeng Yu, Qin Lu, Lun Wang,