Article ID Journal Published Year Pages File Type
1235884 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007 4 Pages PDF
Abstract

Nickel(II) complexes of isatin-3,2′-quinolyl-hydrazones of the type [Ni(L)X] (where X = Cl−, Br−, NO3−, CH3COO− and ClO4−] and their adducts Ni(L)X·2Y [where Y = pyridine or dioxane and X = Cl−, Br−, NO3− and ClO4−] have been synthesized under controlled experimental conditions and characterized by using the modern spectroscopic and physicochemical techniques viz. mass, 1H NMR, IR, electronic, elemental analysis, magnetic moment susceptibility measurements and molar conductance, etc.On the basis of spectral studies a four coordinated tetrahedral geometry is assigned for Ni(L)X type complexes whereas the adducts (Ni(L)X·2Y) were found to have a six coordinated distorted octahedral geometry.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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