Article ID Journal Published Year Pages File Type
1236301 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2006 5 Pages PDF
Abstract

Absorption and fluorescence emission spectra of coumarins 6 and 7 were recorded in solvents with different solvent parameters, viz., dielectric constant ɛ and refractive index n. The fluorescence lifetime of these dyes were measured in butanol at higher values of viscosity over temperature. Experimental ground and excited state dipole moments are determined by means of solvatochromic shift method and also the excited state dipole moments are determined in combination with ground state dipole moments. It was determined that dipole moments of the excited state were higher than those of the ground state in both the molecules.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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