Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1236332 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2006 | 5 Pages |
Abstract
The applicability of (−)-myrtenal as a chiral derivatizing agent in combination with 13C NMR spectroscopy was investigated. 13C NMR was found to be a valuable tool for the identification and enantiomer differentiation of primary amines including β-amino alcohols and vicinal diamines. The enantiomeric excess could be determined via automated deconvolution and integration, and was found to be in good accordance with the expected values even in the cases, when enantiomer differentiation was not possible in 1H NMR spectra.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Francois Dufrasne, Michael Gelbcke, Markus Galanski,