Article ID Journal Published Year Pages File Type
1236476 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2011 8 Pages PDF
Abstract

Electronic absorption and fluorescence spectra of eight hemicyanine dyes were recorded at room temperature in several solvents of different polarity. The spectral data were analyzed using the theory of solvatochromism, based on a dielectric continuum description of the solvent and the classical Onsager cavity model. They were used to evaluate the excited state dipole moment using methods applied by McRae, Lippert, Mataga and Bakhshiev. DFT calculations were carried out to estimate the ground state dipole moment and Onsager cavity radius. The difference in the excited and ground state dipole moments (μe − μg) of the molecule under study is positive. It means that the excited states of the dyes are more polar than the ground state. The increase in dipole moments upon excitation is explained in terms of the nature of the excited state and its resonance structures.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Electronic absorption and fluorescence spectra of hemicyanine dyes were recorded. ► The spectral data were analyzed using the theory of solvatochromism. ► The excited and ground state dipole moments of the dyes were estimated. ► The solute polarizability influences the determination of Δμ. ► The excited state of the compounds is more polar than the ground state.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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