Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1236685 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2010 | 8 Pages |
Abstract
The synthesis of 1,2-di-tert-butyl-3,3-dimethylcyclopropene (I) is performed and its IR and Raman spectra are measured. Optimized geometries of I are obtained at the HF/6-31G* and CCSD/cc-pVDZ levels. The ab initio calculated spectra are used for the assignments of the experimental spectral data. The results obtained are compared with the corresponding data for 3,3-dimethylbut-1-ene and 3,3-dimethylcyclopropene. These experimental data and the total vibrational analysis of I supplement the information obtained in the series of investigations of tert-butyl, trimethylsilyl, trimethylgermyl, trimethylstannyl, and trimethylplumbyl derivatives of 3,3-dimethylcyclopropene.
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Authors
Armin de Meijere, Viktor V. Sokolov, Dmitry S. Yufit, Yurii N. Panchenko, George R. De Maré, Alexander V. Abramenkov, Boris V. Lokshin, Vladimir M. Senyavin,