Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1236733 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2006 | 5 Pages |
Abstract
Herein we report the synthetic route and detailed characterization of the macrocyclic complex [Co(dohpn)(SCN)2] and its linkage isomer (dohpn = 2,3,9,10-tetramethyl-1,4,8,11-tetraazaundecane-1,3,8,10-tetraen-11-ol-1-olate and py = pyridine) based on analytical, spectroscopic and electrochemical methods. Structural, vibrational and electronic features are discussed and a coherent assignment is proposed on the basis of semi-empirical theoretical calculations.
Related Topics
Physical Sciences and Engineering
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Analytical Chemistry
Authors
Leandro J. Cavichiolo, Tai Hasegawa, Fábio S. Nunes,