Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1236760 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2010 | 5 Pages |
Abstract
The anion binding properties of two title tri(indolyl)methane compounds have been evaluated by using UV–vis absorption and fluorescence spectroscopy. Different from 3-linked receptor which exhibited faint even no obvious spectral response to anions, 2-linked receptor can bind F−, AcO− and H2PO4−, with the bathochromic shifts of the UV absorption and fluorescence quenching. This selectivity will be attributed to suitable steric array of NH binding sites of 2-linked receptor, which helps to form multiple hydrogen bonding interactions with anions.
Related Topics
Physical Sciences and Engineering
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Authors
Wei Wei, Yong Guo, Jian Xu, Shijun Shao,