| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1236973 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2005 | 13 Pages |
Abstract
The crystal structure of diguanidinium hydrogenarsenate monohydrate has been found to belong to the P4¯21/c space group of the tetragonal system, with Z = 8, a = 17.114(2) Å, c = 7.3500(10) Å. In this complex, a network of hydrogen bonds links water molecules and hydrogenarsenate ions. The hydrogenarsenate ions form hydrogen-bonded chains along the crystallographic c-axis. Detailed vibrational studies have been carried out (FTIR and FT-Raman on powder samples, polarized FTIR microscope on a small single crystal at room temperature). The vibrational spectra are discussed in relation to the crystal structure. Calorimetric (DSC) studies have been performed, but no phase transition was found in the temperature range 100–350 K.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
M. Drozd, J. Baran, A. Pietraszko,