Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1237018 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2005 | 7 Pages |
Abstract
The formation and adsorption of enolic species on a palladium promoted Ag/Al2O3 catalyst (denoted Ag-Pd/Al2O3) during the selective catalytic reduction (SCR) of NOx by C3H6 has been studied by means of DRIFTS and density functional calculations. The structure of the enolic species adsorbed on Ag-Pd/Al2O3 catalyst has been established based on the in situ DRIFTS spectra and simulated results. The reaction mechanism from C3H6 to enolic species on Ag-Pd/Al2O3 catalyst was proposed and the hypothesis about the Pd promotion was discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Hongwei Gao, Hong He, Qingcai Feng, Jin Wang,