Article ID Journal Published Year Pages File Type
1237089 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2009 4 Pages PDF
Abstract
Sitting-atop (SAT) complexes, [TiCl4(H2T(X)PP)], formed from the reaction between meso-tetraarylporphyrins (H2T(X)PP) and TiCl4. Kf and ΔG° for SAT complexes are directly related to lower steric effect and the better electron donation for the aryl rings of the porphyrins.
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Physical Sciences and Engineering Chemistry Analytical Chemistry
Preview
Spectrophotometric studies of the thermodynamics of sitting-atop complexation between free base meso-tetraarylporphyrins and titanium(IV) chloride
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