Article ID Journal Published Year Pages File Type
1237132 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2005 6 Pages PDF
Abstract
Manganese(II) complexes having the general composition Mn(L)2X2 [where L = isopropyl methyl ketone semicarbazone (LLA), isopropyl methyl ketone thiosemicarbazone (LLB), 4-aminoacetophenone semicarbazone (LLC) and 4-aminoacetophenone thiosemicarbazone (LLD) and X = Cl−, 1/2SO42−] have been synthesized. All the complexes were characterized by elemental analyses, molar conductance, magnetic moment susceptibility, EI-mass, 1H NMR, IR, EPR and electronic spectral studies. All the complexes show magnetic moments corresponding to five unpaired electrons. The possible geometries of the complexes were assigned on the basis of EPR, electronic and infrared spectral studies.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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