Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1237225 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2010 | 5 Pages |
Abstract
Electron paramagnetic resonance (EPR) study of Cu2+ doped bis (glycinato) Mg (II) monohydrate single crystals is carried out at room temperature. Copper enters the lattice substitutionally and is trapped at two magnetically inequivalent sites. The observed spectra are fitted to a spin-Hamiltonian of rhombic symmetry with the following values of the parameters: Cu2+ (I), gx = 2.1577 ± 0.0002, gy = 2.2018 ± 0.0002, gz = 2.3259 ± 0.0002, Ax = (87 ± 2) Ã 10â4 cmâ1, Ay = (107 ± 2) Ã 10â4 cmâ1, Az = (141 ± 2) Ã 10â4 cmâ1; Cu 2+ (II), gx = 2.1108 ± 0.0002, gy = 2.1622 ± 0.0002, gz = 2.2971 ± 0.0002, Ax = (69 ± 2) Ã 10â4 cmâ1, Ay = (117 ± 2) Ã 10â4 cmâ1and Az = (134 ± 2) Ã 10â4 cmâ1. The ground state wave function of the Cu2+ ion in this lattice is evaluated to be predominantly |x2 â y2. The g-factor anisotropy is also calculated and compared with the experimental value. With the help of the optical absorption study, the nature of bonding in the complex is discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Prashant Dwivedi, Ram kripal,