Article ID Journal Published Year Pages File Type
1237228 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2010 6 Pages PDF
Abstract

Vanadate–tellurate vitreous systems with composition (1 − x)TeO2·xV2O5 where x = 0.3 and 0.4 have been prepared by the conventional melt-quench method. The structural aspects have been investigated using FTIR spectroscopy and the density functional theory (DFT) calculations.The present study provides the interesting information concerning devitrification behavior of the vanadate–tellurate vitreous system which occur Te2V2O9 crystalline phase. The structure of the heat-treated glasses was found to consist mainly of rings containing [TeO3], [TeO4], [VO4] and some [VO5] structural units.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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